Where it sparks
Choosing a restaurant takes four minutes, because neither of you is willing to suggest the cheap place. You book the room with good light, order more than you need, and talk to the waiter like a guest.
Zodiac compatibility
Synastry compares two birth charts and describes the mechanics of a pair. It explains why one of you wants to talk a thing through at midnight while the other needs eight hours of silence first. Sun signs are the first layer of that, a sketch of temperament.

Leo
Leo
Your pair · ♌︎ Leo ♌︎ Leo
Two Leos make a room warmer and louder than it was a minute ago. The generosity is real, and so is the quiet contest over who stands in the middle of it. It holds when each of you has a stage of your own and comes home to clap for the other.
Heat of the pair · Warm
Choosing a restaurant takes four minutes, because neither of you is willing to suggest the cheap place. You book the room with good light, order more than you need, and talk to the waiter like a guest.
Money is where the sun goes down. Two people who round up, tip big and hate looking small can spend a month of rent on one weekend. The argument is never about the sum.
The verdict
Big love, and it lasts exactly as long as the applause goes both ways.
All of it at once
Twelve by twelve, with the traditional logic of the elements behind the colour. Warm squares are the easy pairs and cool squares are the interesting ones, and that is not the same thing as good ones and bad ones.
Heat runs from one to five and comes from the tradition of elements, not from a study of couples. It describes how quickly two temperaments recognise each other, and nothing at all about how long anybody stays.
Reading it
Start with temperament, not verdict
Read both sun signs as two speeds and two appetites. The question is not whether they match, it is where each of you naturally goes when tired, bored or in love.
Look at the friction on purpose
Every pair has a seam. Name it while things are calm, in plain language, and you convert a recurring fight into a known difference that both of you can plan around.
Then go past the Sun
Moons show whether you comfort each other correctly, Venus and Mars show desire and pace. Two charts can clash by sun sign and fit beautifully everywhere it matters daily.

Questions
No. A percentage is a number invented by whoever coded the page, and there is no measurement behind it, no scale it belongs to, and no way to check it against anything real. Ninety one percent and sixty four percent are both storytelling. Read the description of how the two temperaments meet, ignore the score, and notice that the text is usually more honest than the number attached to it.
They do not. Relationships are decided by whether two people tell each other the truth, repair after fights, want roughly the same decade, and keep choosing each other when it is inconvenient. Astrology can give you vocabulary for the differences, which genuinely helps some couples argue better. Using a chart to end something that works, or to excuse something that hurts, is the one way to make it harmful.
The Moons and the way they handle each other in a bad week, Venus and Mars for desire and rhythm, Mercury for whether conversation feels like rest or work. Beyond that, the houses your planets fall into in each other's charts, which describes where you actually show up in one another's life. Sun signs are the cover of the book and there are two hundred pages after it.
It is not, and the traditional lists were built on element logic rather than on couples. Plenty of long marriages sit on combinations that every table calls difficult, because difficulty is not the same as doom, and similarity is not the same as love. Take the description of the friction as a heads up about what you will need to talk about, then keep living with the person in front of you.
Read here as a language of symbols. Medical, legal and financial questions belong with a professional.
Where next
Two Moons and two Venuses say far more about a daily life together than two Suns ever will. Build both charts and the conversation changes.